Imbibition in mesoporous silica: rheological concepts and experiments on water and a liquid crystal

We present, along with some fundamental concepts regarding imbibition of liquids in porous hosts, an experimental, gravimetric study on the capillarity-driven invasion dynamics of water and of the rod-like liquid crystal octyloxycyanobiphenyl (8OCB) in networks of pores a few nanometers across in monolithic silica glass (Vycor). We observe, in agreement with theoretical predictions, square root of time invasion dynamics and a sticky velocity boundary condition for both liquids investigated. Temperature-dependent spontaneous imbibition experiments on 8OCB reveal the existence of a paranematic phase due to the molecular alignment induced by the pore walls even at temperatures well beyond the clearing point. The ever present velocity gradient in the pores is likely to further enhance this ordering phenomenon and prevent any layering in molecular stacks, eventually resulting in a suppression of the smectic phase in favor of the nematic phase.Comment: 18 pages, 8 figure

Dynamics of cholesteric structures in an electric field

Motivated by Lehmann-like rotation phenomena in cholesteric drops we study the transverse drift of two types of cholesteric fingers, which form rotating spirals in thin layers of cholesteric liquid crystal in an ac or dc electric field. We show that electrohydrodynamic effects induced by Carr-Helfrich charge separation or flexoelectric charge generation can describe the drift of cholesteric fingers. We argue that the observed Lehmann-like phenomena can be understood on the same basis.Comment: 4 pages, 4 figures, submitted to PR

Biasing a ferronematic-a new way to detect weak magnetic field

The magnetic properties of a ferronematic, i.e., a nematic liquid crystal doped with magnetic nanoparticles in low volume concentration are studied, with the focus on the ac magnetic susceptibility. A weak dc bias magnetic field (a few Oe) applied to the ferronematic in its isotropic phase increases the ac magnetic susceptibility considerably. Passage of the isotropic-to-nematic phase transition resets this enhancement irreversibly (unless the dc bias field is applied again in the isotropic phase). © 2016 The Royal Society of Chemistry

Recording 2-D Nutation NQR Spectra by Random Sampling Method

The method of random sampling was introduced for the first time in the nutation nuclear quadrupole resonance (NQR) spectroscopy where the nutation spectra show characteristic singularities in the form of shoulders. The analytic formulae for complex two-dimensional (2-D) nutation NQR spectra (I = 3/2) were obtained and the condition for resolving the spectral singularities for small values of an asymmetry parameter η was determined. Our results show that the method of random sampling of a nutation interferogram allows significant reduction of time required to perform a 2-D nutation experiment and does not worsen the spectral resolution

Dielectric properties of nematic liquid crystals with Fe₃O₄ nanoparticles in direct magnetic field

Researched within the frequency range 10⁻¹–10⁶ Hz were dielectric properties of pure 6CHBT liquid crystals and 6CHBT ones with the impurity of Fe₃O₄ nanoparticles that have the mean diameter 5 nm and weight concentration 10⁻⁴ %. The study was performed without and under the influence of direct magnetic field with the induction 0.45 and 0.60 T. It has been shown that the magnetic field influences on the parameters of the near-electrode area of liquid crystal. In the case of liquid crystal with magnetic nanoparticles, the parameter changes caused by the magnetic field depend on the induction value